Primary Key..
1.It will not accept null values.
2.There will be only one primary key in a table.
3.Clustered index is created in Primary key.
4.Primary key allows each row in a table to be uniquely identified and ensures that no duplicate rows exist.

Unique Key..
1.Null values are accepted.
2.More than one unique key will be there in a table.
3.Non-Clustered index is created in unique key.
4.Unique key constraint is used to prevent the duplication of key values within the rows of a table and allow null values.